Furyk, the 2003 U.S. Open champion, finished second with seven skins while 2003 Masters winner Mike Weir won two skins. Tim Clark avoided being shutout and captured one skin.
The chip-off on the 18th hole was good for a carry-over of four skins. Goosen was closest to the hole out of a greenside bunker to win the skins.
The Exelon Invitational is an annual skins match where the pros compete for a purse of $300,000. A $100,000 check was donated to the Boys & Girls Clubs of Philadelphia this year.
Past participants have included Phil Mickelson, David Toms, David Duval, Davis Love III, Nick Price, Jesper Parnevik and Justin Leonard.